(-)-(R)-1,2-Methano-3-octanol
- Sweet matsutake-like (mushroom-like) odor,
close to natural (R)-matsutakeol (natural
1-octen-3-ol)
The racemate
is described as Unpleasant sweet-sour, fatty,
woody, rosy odor, lacking in mushroom-like
aspect in natural (R)-matsutakeol (natural
1-octen-3-ol)
=
(-)-(R)-1-cyclopropylhexan-1-ol
Ref: Hiroki
Asao, Hiroyuki Sakauchi, Shigefumi Kuwahara and
Hiromasa Kiyota, Synthesis and odor description
of optically active cyclopropanated analogues of
geraniol, nerol, nor-leaf alcohol, and matsutake
alcohol, Tetrahedron: Asymmetry, 18 (2007)
537541
|
|
(+)-(S)-1,2-Methano-3-octanol
- Humid mossy rosy odor, no mushroom character
as found in the racemate
The racemate
is described as Unpleasant sweet-sour, fatty,
woody, rosy odor, lacking in mushroom-like
aspect in natural (R)-matsutakeol (natural
1-octen-3-ol)
=
(+)-(S)-1-cyclopropylhexan-1-ol
Ref: Hiroki
Asao, Hiroyuki Sakauchi, Shigefumi Kuwahara and
Hiromasa Kiyota, Synthesis and odor description
of optically active cyclopropanated analogues of
geraniol, nerol, nor-leaf alcohol, and matsutake
alcohol, Tetrahedron: Asymmetry, 18 (2007)
537541
|
|