-(1'r,3's,6's)-3'-methyl-norlimbanol.gif)
(+)-(1'R,3'S,6'S)-
Limbanol® =
(+)-(1'R,3'S,6'S)-3'-methyl-norlimbanol
-
woody-amber
odor of extraordinary intensity, together with a
slight transpiration side note
=
(+)-(1'R,3'S,6'S)-1-(2',2',3',6'-tetramethyl-1'-cyclohexyl)-3-hexanol
Note that the
C-3 position is epimeric, so this actually is a
mixture of (1'R,3S,3'S,6'S) &
(1'R,3R,3'S,6'S) isomers
Ref:
Schulte-Elte, et al., Optically active aliphatic
alcohols and their use as perfuming ingredients,
United States Patent 6,054,426, April 25,
2000
Limbanol is a
trademark of Firmenich SA
|
|
-(1's,3'r,6'r)-3'-methyl-norlimbanol.gif)
(-)-(1'S,3'R,6'R)-Limbanol®
=
(-)-(1'S,3'R,6'R)-3'-methyl-norlimbanol
-
a much
weaker odor, albeit of similar character to the
(+)-(1'R,3'S,6'S)-isomer
=
(-)-(1'S,3'R,6'R)-1-(2',2',3',6'-tetramethyl-1'-cyclohexyl)-3-hexanol
Note that the
C-3 position is epimeric, so this actually is a
mixture of (1'S,3S,3'R,6'R) &
(1'S,3R,3'S,6'R) isomers
Ref:
Schulte-Elte, et al., Optically active aliphatic
alcohols and their use as perfuming ingredients,
United States Patent 6,054,426, April 25,
2000
Limbanol is a
trademark of Firmenich SA
|
|