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-3-butylhexahydrophthalide.gif)
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(3S,3aS,7aR)-3-Butylhexahydrophthalide
- sweet and sickly
Also known
as:
(3S,3aS,7aR)-3-butylhexahydro-2-benzofuran-1(3H)-one
It should be
noted that we only show two of the eight
3-butylhexahydrophthalide stereoisomers. Of the
two isomers shown here, only the odorless
3R,3aR,7aS isomer is found in celery, celeriac,
and fennel.
Ref:
Bartschat, D.; Wust, M.; Hanssum, H.; Mosandl,
A. Stereoisomeric flavor compounds LXXVII:
3-Butylhexahydrophthalides: Simultaneous
enantioselective analysis, structure
elucidation, and sensorial properties of the
stereoisomers; J. High Resolut. Chromatogr.
1997, 20, 251-256; Dietmar Bartschat, Thomas
Beck, and Armin Mosandl, Stereoisomeric Flavor
Compounds. 79. Simultaneous Enantioselective
Analysis of 3-Butylphthalide and
3-Butylhexahydrophthalide Stereoisomers in
Celery, Celeriac, and Fennel, J. Agric. Food
Chem. 1997, 45, 4554-4557
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(3R,3aR,7aS)-3-Butylhexahydrophthalide
- odorless
Also known
as:
(3R,3aR,7aS)-3-butylhexahydro-2-benzofuran-1(3H)-one
It should be
noted that we only show two of the eight
3-butylhexahydrophthalide stereoisomers. Of the
two isomers shown here, only the odorless
3R,3aR,7aS isomer is found in celery, celeriac,
and fennel.
Ref:
Bartschat, D.; Wust, M.; Hanssum, H.; Mosandl,
A. Stereoisomeric flavor compounds LXXVII:
3-Butylhexahydrophthalides: Simultaneous
enantioselective analysis, structure
elucidation, and sensorial properties of the
stereoisomers; J. High Resolut. Chromatogr.
1997, 20, 251-256; Dietmar Bartschat, Thomas
Beck, and Armin Mosandl, Stereoisomeric Flavor
Compounds. 79. Simultaneous Enantioselective
Analysis of 3-Butylphthalide and
3-Butylhexahydrophthalide Stereoisomers in
Celery, Celeriac, and Fennel, J. Agric. Food
Chem. 1997, 45, 4554-4557
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