-1'r,6's-5-methyl-norlimbanol.gif)
(1'R,6'S)-(+)-5-methyl-norlimbanol
- woody, resembles (+)-1'R,3S,6'S-norlimbanol
(strong very elegant woody-amber note)
(Schulte-Elte, et al.); also described as highly
diffusible, sharp amber fragrance with slight
camphorous side note (Ohmoto et al. for a 95.2:
4.8 % ratio of trans/cis isomers)
=
(+)-(1'R,6'S)-5-methyl-1-(2',2',6'-trimethyl-1'-cyclohexyl)-3-hexanol
Note that the
C-3 position is epimeric, so this actually is a
mixture of (1'R,3S,6'S) & (1'R,3R,6'S)
isomers
Ref:
Schulte-Elte, et al., Optically active aliphatic
alcohols and their use as perfuming ingredients,
United States Patent 6,054,426, April 25, 2000,
assigned to Firmenich; Ohmoto, Tatsuya; Shimada,
Akemi; Yamamoto,
Takeshi;
Propanol derivatives and perfumes containing the
same, United States Patent RE37,159 May 1, 2001
& United States Patent 5,250,512, Oct. 5,
1993, Assigned to Takasago International
Corp.
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-1's,6'r-5-methyl-norlimbanol.gif)
(1'S,6'R)-(-)-5-methyl-norlimbanol
-
very weak
and devoid of animal character (Schulte-Elte, et
al.); also described as a faint woody odor with
a little moldiness (Ohmoto et al. for a 95.1:
4.9 % ratio of trans/cis isomers)
=
(-)-(1'S,6'R)-5-methyl-1-(2',2',6'-trimethyl-1'-cyclohexyl)-3-hexanol
Note that the
C-3 position is epimeric, so this actually is a
mixture of (1'S,3R,6'R) & (1'S,3S,6'R)
isomers
Ref:
Schulte-Elte, et al., Optically active aliphatic
alcohols and their use as perfuming ingredients,
United States Patent 6,054,426, April 25, 2000,
assigned to Firmenich; Ohmoto, Tatsuya; Shimada,
Akemi; Yamamoto,
Takeshi;
Propanol derivatives and perfumes containing the
same, United States Patent RE37,159 May 1, 2001
& United States Patent 5,250,512, Oct. 5,
1993, Assigned to Takasago International
Corp.
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