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-6-acetoxycineole.gif)
(1S,4R,6S)-(+)-6-Acetoxy-1,8-cineole
- woody (weak)
Ref: H. K.
Kubota, et. al., J. Agric. Food Chem., 47,
No. 2, 685-689 (1999)
Also
called
(1S,4R,2S)-(+)-2-Acetoxy-1,8-cineole
In
contrast to Kubota's report, Mitsuo Miyazawa
and Yuya Hashimoto (Microbial resolution of
racemic 2-endo-acetoxy-1,8-cineole by
Glomerella cingulata, Tetrahedron: Asymmetry,
Volume 12, Issue 22, 10 December 2001, Pages
3185-3187) report that "both
(+)-2-endo-acetoxy-1,8-cineole and
(-)-2-endo-hydroxy-1,8-cineole could be
quantitatively obtained in enantiomerically
pure form (yield 50%; e.e. 100%). In
addition, the odor differences between the
enantiomers are also described. In both
compounds (acetoxy and hydroxy), the
(+)-enantiomers tended to have more bright,
light and sweet odors than their
(-)-antipodes."
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-6-acetoxycineole.gif)
(1R,4S,6R)-(-)-6-Acetoxy-1,8-cineole
- woody, Alpinia galanga like and stronger
than the (1S,4R,6S)- isomer
Ref: H. K.
Kubota, et. al., J. Agric. Food Chem., 47,
No. 2, 685-689 (1999)
Also
called
(1R,4S,2R)-(-)-2-Acetoxy-1,8-cineole
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-6-acetoxycineole.gif)
(1S,4R,6R)-6-Acetoxy-1,8-cineole
- weak
Also
called
(1S,4R,2R)-2-Acetoxy-1,8-cineole
Ref: H. K.
Kubota, et. al., J. Agric. Food Chem., 47,
No. 2, 685-689 (1999)
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-6-acetoxycineole.gif)
(1R,4S,6S)-6-Acetoxy-1,8-cineole
- fruity, sweet
Also called
(1R,4S,2S)-2-Acetoxy-1,8-cineole
Ref: H. K.
Kubota, et. al., J. Agric. Food Chem., 47, No.
2, 685-689 (1999)
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