-(6R)-3,4-Didehydro-7,8-dihydro-g-ionone.gif)
(-)-(6R)-3,4-Didehydro-7,8-dihydro-gamma-ionone
- weaker on blotter than (+)-(S)-isomer, fruity,
agrestic, floral, ionone- and damascone-like,
slightly woody, and saffron-like
Odor
threshold = 99.4 ng/L in air
=
(-)-4-[(1R)-6,6-dimethyl-2-methylenecyclohex-3-en-1-yl]butan-2-one
Ref: Stefano
Serra, Claudio Fuganti, and Elisabetta Brenna,
Synthesis, Olfactory Evaluation, and
Determination of the Absolute Configuration of
the 3,4-Didehydroionone Stereoisomers, Helvetica
Chimica Acta, Vol. 89 (2006),
1110-1122.
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-(6S)-3,4-Didehydro-7,8-dihydro-g-ionone.gif)
(+)-(6S)-3,4-Didehydro-7,8-dihydro-gamma-ionone
- stronger on blotter than (-)-(R)-isomer,
woody-powdery, ionone, slightly fruity-floral,
more pronounced ionone character than
(-)-(R)-isomer.
Odor
threshold = 92 ng/L in air
=
(+)-4-[(1S)-6,6-dimethyl-2-methylenecyclohex-3-en-1-yl]butan-2-one
Ref: Stefano
Serra, Claudio Fuganti, and Elisabetta Brenna,
Synthesis, Olfactory Evaluation, and
Determination of the Absolute Configuration of
the 3,4-Didehydroionone Stereoisomers, Helvetica
Chimica Acta, Vol. 89 (2006),
1110-1122.
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