-(-)-dihydro-irone.gif)
(1'R,3'R,6'R)-(E)-(-)-dihydroirone
- Woody, powdery, incense.
The
description given for racemate is: iris-violet
note, powdery, balsamic, reminiscent of myrrh,
woody, exceptional strength and tenacity
odor
=
(1'R,3'R,6'R)-(E)-(-)-
4-(2',2',3',6'-Tetramethyl-cyclohexyl)-but-3-en-2-one
Ref:
Chapuis;Christian;
Schulte-Elte; Karl-Heinrich; Pamingle; Herve;
Margot; Christian, United States Patent
5,118,865, June 2, 1992; Christian Chapuis &
Robert Brauchli, Preparation of Optically Active
Flowery and Woody-Like Odorant Ketones via
Corey-Chaykovsky Oxiranylation: Irones and
Analogues , Helv.Chim.Acta 1993, 76: 2070-2088;
Elisabetta Brenna, Claudio Fuganti and Stefano
Serra, Enantioselective perception of chiral
odorants, Tetrahedron: Asymmetry, 14, 142
(2003)
|
|
-(-)-dihydro-irone.gif)
(1'S,3'S,6'S)-(E)-(+)-dihydroirone
- iris-irone note with a very warm
balsamic-myrrh, woody character. The violet-iris
character is more pronounced than in
(1'R,3'R,6'R)-(E)-(-)-enantiomer or the racemate
and the odor note is even stronger
=
(1'S,3'S,6'S)-(E)-(+)-4-(2',2',3',6'-Tetramethyl-cyclohexyl)-but-3-en-2-one
Ref:
Chapuis;Christian;
Schulte-Elte; Karl-Heinrich; Pamingle; Herve;
Margot; Christian, United States Patent
5,118,865, June 2, 1992; Christian Chapuis &
Robert Brauchli, Preparation of Optically Active
Flowery and Woody-Like Odorant Ketones via
Corey-Chaykovsky Oxiranylation: Irones and
Analogues , Helv.Chim.Acta 1993, 76: 2070-2088;
Elisabetta Brenna, Claudio Fuganti and Stefano
Serra, Enantioselective perception of chiral
odorants, Tetrahedron: Asymmetry, 14, 142
(2003)
|
|