(-)-(S)-Oxo-muscolide
- possesses a weak musk note, without animalic
character, and is dominated by an odour
reminiscent of ironed linen.
=
(-)-(14S)-14-methyl-12-oxo-15-pentadecanolide
Ref:
B.
Bollbuck, P. Kraft, W. Tochtermann, Nature-like
Odorants by Stereoselective Ring Enlargement of
Cyclohexanone and Cyclododecanone, Tetrahedron
1996, 52, 4581-4592; see also Elisabetta Brenna,
Claudio Fuganti and Stefano Serra,
Enantioselective perception of chiral odorants,
Tetrahedron: Asymmetry, 14, 142
(2003)
|
|
(+)-(R)-Oxo-muscolide
- slightly musky and sweet, but not
erogenous-animalic.
=
(+)-(14R)-14-methyl-12-oxo-15-pentadecanolide
Ref:
B.
Bollbuck, P. Kraft, W. Tochtermann, Nature-like
Odorants by Stereoselective Ring Enlargement of
Cyclohexanone and Cyclododecanone, Tetrahedron
1996, 52, 4581-4592; see also Elisabetta Brenna,
Claudio Fuganti and Stefano Serra,
Enantioselective perception of chiral odorants,
Tetrahedron: Asymmetry, 14, 142
(2003)
|
|